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This is caused by the degassing present or absent from coffee. During the roasting process, sugars, proteins, and fats are chemically broken down and release CO2. Because coffee is porous, and because of the pressure inside the bean, the CO2 slowly escapes (degassing) which will leave the coffee inert to boiling water after it has aged. another sign is the presence of oils which will show up on the beans surface after a coffee has sat for some time, reguardless of roast level. (light roasts show oils too). a final test is to throw the bean on the ground, and if it pops and “explodes” it will tell you whether it still has CO2 still trapped in the porous structure.
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